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What is Electronegativity?

Illustration showing two atoms sharing electrons with one pulling more strongly
Electronegativity determines how atoms share electrons in chemical bonds

Electronegativity is a measure of how strongly an atom can attract electrons when it forms a chemical bond. Think of it like a game of tug-of-war between atoms - the atom with higher electronegativity pulls the shared electrons closer to itself.

This concept helps us understand how atoms will behave when they form molecules. It explains why some bonds are strong while others are weak, and why some substances dissolve in water while others don't.

The Electronegativity Scale

Diagram showing the Pauling electronegativity scale with example elements
The Pauling scale measures electronegativity from 0.7 to 4.0

Scientists use different scales to measure electronegativity, but the most common is the Pauling scale. On this scale, values range from about 0.7 (for very weak attraction) to 4.0 (for very strong attraction).

Fluorine is the most electronegative element with a value of 4.0, while francium is the least electronegative at 0.7. Most elements fall somewhere in between these values.

Low Electronegativity

0.7 - 1.5

Metals like sodium, potassium, and calcium

Medium Electronegativity

1.6 - 2.5

Elements like silicon, carbon, and hydrogen

High Electronegativity

2.6 - 4.0

Nonmetals like oxygen, nitrogen, and fluorine

Periodic Table Electronegativity Chart

Periodic table colored by electronegativity values with a gradient from low to high
Electronegativity trends in the periodic table

Electronegativity follows specific patterns in the periodic table. Generally, electronegativity increases from left to right across a period and decreases from top to bottom within a group.

This means that elements on the right side of the periodic table (nonmetals) tend to have high electronegativity, while elements on the left side (metals) have low electronegativity.

Electronegativity Increases →
Across a Period
Electronegativity Decreases
Down a Group

Electronegativity Values and Trends

Graph showing electronegativity trends across period 3 with elements Na, Mg, Al, Si, P, S, Cl, Ar
Electronegativity increases across a period in the periodic table

Knowing electronegativity values helps predict the type of bond that will form between atoms:

0.0-0.4

Nonpolar Covalent

Equal sharing of electrons

0.5-1.9

Polar Covalent

Unequal sharing of electrons

≥2.0

Ionic Bond

Electron transfer occurs

When two atoms have similar electronegativity values (difference less than 0.5), they form nonpolar covalent bonds with equal sharing. With larger differences (0.5-1.9), polar covalent bonds form. When the difference is 2.0 or more, ionic bonds typically form.

Element Symbol Electronegativity
Fluorine F 4.0
Oxygen O 3.5
Nitrogen N 3.0
Chlorine Cl 3.0
Carbon C 2.5
Hydrogen H 2.1
Sodium Na 0.9
Potassium K 0.8

Electronegativity Quiz

Test your knowledge about electronegativity with this quiz! Answer all 5 questions to see how much you've learned.

1. What does electronegativity measure?
2. Which element has the highest electronegativity value?
3. How does electronegativity change as you move from left to right across the periodic table?
4. What type of bond forms when two atoms have very different electronegativity values (difference ≥ 2.0)?
5. Which scientist developed the most commonly used electronegativity scale?

Frequently Asked Questions

Here are answers to some common questions about electronegativity:

Science Trivia

Discover some interesting facts about electronegativity!

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