Skip to main content
Skip to main content

What is Chemical Equilibrium?

Visual representation of chemical equilibrium
Illustration showing the balance of reactants and products at equilibrium

Chemical equilibrium is like a perfectly balanced seesaw! It's when a chemical reaction reaches a point where the forward reaction (reactants turning into products) happens at exactly the same rate as the reverse reaction (products turning back into reactants).

At equilibrium, the amounts of reactants and products don't change anymore, but both reactions are still happening. It's like two teams playing tug-of-war where both sides are equally strong - the rope doesn't move, but both teams are still pulling!

The Equilibrium Constant (K)

Diagram showing the equilibrium constant
Diagram of the equilibrium constant formula

The equilibrium constant (K) is a special number that tells us how much products and reactants are present when a reaction reaches equilibrium. It's like a "balance score" for the reaction!

Scientists calculate K using this simple rule:

K = [Products] / [Reactants]

Here's what K tells us:
• If K is large (K > 1): More products than reactants at equilibrium
• If K is small (K < 1): More reactants than products at equilibrium
• If K = 1: Equal amounts of products and reactants

1

Law of Mass Action

The scientific rule that defines how K is calculated

2

Constant Value

K only changes with temperature

3

Reaction Direction

K tells us which way the reaction "prefers" to go

Kc and Kp - Two Types of Constants

Illustration showing Kc for solutions and Kp for gases
Kc for concentration in solutions and Kp for pressure in gases

There are two main types of equilibrium constants:

Kc: This is used when we measure concentrations (how much substance is dissolved in a solution). For a reaction: aA + bB ⇌ cC + dD

Kc = [C]ᶜ [D]ᵈ / [A]ᵃ [B]ᵇ

Kp: This is used for gases, when we measure partial pressures instead of concentrations. For the same reaction:

Kp = (Pc)ᶜ (Pd)ᵈ / (Pa)ᵃ (Pb)ᵇ

Why two different constants? Because gases behave differently than substances in solution! Kc and Kp are related but not the same. They can be converted using temperature and the change in number of gas molecules.

Reaction Quotient (Q)

Traffic light analogy for reaction quotient
Traffic light analogy for reaction quotient

The reaction quotient (Q) is like K's younger sibling! It has the same formula as K, but we calculate it at any point during the reaction, not just at equilibrium. Q tells us which way the reaction needs to go to reach equilibrium.

Q < K

Reaction will move forward (make more products)

Q = K

Reaction is at equilibrium

Q > K

Reaction will move backward (make more reactants)

Think of Q as a GPS for chemical reactions! It tells the reaction: "You need to go this way to reach your destination (equilibrium)!" Scientists use Q to predict how reactions will behave before they reach balance.

Equilibrium Quiz

Test your knowledge with this equilibrium quiz! Answer all 5 questions to see how much you've learned.

1. What does it mean when a reaction is at equilibrium?
2. What does a large equilibrium constant (K > 1) tell us?
3. When do we use Kp instead of Kc?
4. What does it mean if Q < K for a reaction?
5. Which factor changes the value of the equilibrium constant K?

Frequently Asked Questions

Here are answers to some common questions about chemical equilibrium:

Fun Equilibrium Trivia

Discover some amazing facts about chemical equilibrium!

Copyright © 2025 Workybooks. Made with ♥ in California.