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What Are Halogens?

Illustration showing the five halogen elements with their symbols and common forms
The halogen elements: fluorine, chlorine, bromine, iodine, and astatine

Halogens are a special group of elements on the periodic table that are known for being highly reactive. The word "halogen" comes from Greek words meaning "salt former" because these elements easily form salts when they react with metals.

There are five halogens: fluorine (F), chlorine (Cl), bromine (Br), iodine (I), and astatine (At). These elements are never found alone in nature because they're so reactive—they're always combined with other elements in compounds.

Halogens in the Periodic Table

Periodic table with Group 17 elements highlighted in bright color
Halogens are located in Group 17 of the periodic table

In the periodic table, elements are arranged in columns called groups and rows called periods. The halogens are found in Group 17, which is the second column from the right.

All halogens have seven electrons in their outer shell, which makes them highly likely to gain one more electron to become stable. This is why they're so reactive!

F
Fluorine
Atomic Number: 9
Cl
Chlorine
Atomic Number: 17
Br
Bromine
Atomic Number: 35
I
Iodine
Atomic Number: 53
At
Astatine
Atomic Number: 85

As we move down the group from fluorine to astatine, the elements become less reactive. Fluorine is the most reactive halogen, while astatine is the least reactive.

Properties of Halogens

Visual comparison of halogen properties showing color changes and state changes down the group
Halogens show trends in physical properties as you move down the group

Halogens share several important properties because they all have seven electrons in their outer shell:

Common Properties of Halogens:

  • They are highly reactive nonmetals
  • They have seven valence electrons
  • They form diatomic molecules (two atoms bonded together)
  • They form salts when combined with metals
  • They become less reactive as you move down the group
  • Their melting and boiling points increase down the group

Halogens also show interesting trends in their physical appearance. Fluorine is a pale yellow gas, chlorine is a greenish-yellow gas, bromine is a reddish-brown liquid, iodine is a dark purple solid, and astatine is a black solid.

Halogen Examples

Common everyday products containing halogens like table salt, disinfectants, and non-stick pans
Many everyday products contain halogen compounds

While we rarely encounter pure halogens in daily life (they're too reactive!), we use many compounds containing halogens every day:

F

Fluorine Compounds

Toothpaste (fluoride), non-stick pans (Teflon)

Cl

Chlorine Compounds

Table salt (sodium chloride), swimming pool disinfectants

Br

Bromine Compounds

Flame retardants, photographic film

I

Iodine Compounds

Disinfectants (iodine solution), table salt (iodized salt)

These compounds are much safer and more stable than the pure halogen elements. For example, while chlorine gas is poisonous, sodium chloride (table salt) is essential for our bodies!

Uses of Halogens

Various applications of halogens in medicine, water treatment, and technology
Halogens have many important applications in our daily lives

Halogens and their compounds have countless uses in industry, medicine, and everyday life:

Important Uses of Halogens:

  • Water purification: Chlorine kills harmful bacteria in drinking water and swimming pools
  • Medicine: Fluoride prevents tooth decay, iodine is used as disinfectant
  • Agriculture: Chlorine compounds are used in pesticides
  • Technology: Halogens are used in lighting and electronics
  • Manufacturing: Used in plastics, solvents, and refrigerants

While halogens are incredibly useful, some halogen compounds can be harmful to the environment. For example, chlorofluorocarbons (CFCs) were once used in refrigerators and aerosol sprays but were found to damage the ozone layer. Today, safer alternatives are used instead.

Halogen Quiz

Test your knowledge about halogens with this quiz! Answer all 5 questions to see how much you've learned.

1. Which group of the periodic table do halogens belong to?
2. Which halogen is a liquid at room temperature?
3. Why are halogens so reactive?
4. Which halogen is used to prevent tooth decay?
5. What does the word "halogen" mean?

Frequently Asked Questions

Here are answers to some common questions about halogens:

Science Trivia

Discover some amazing facts about halogens!

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