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What is Vapor Pressure?

Diagram showing vapor pressure in a closed container
Illustration of vapor pressure concept in a closed container

Vapor pressure is the pressure created by the gas (vapor) above a liquid in a closed container. When a liquid is in a closed space, some molecules escape from the liquid's surface and become gas. These gas molecules bounce around and push against the container's walls, creating vapor pressure.

Think of a soda bottle before you open it. The fizz (carbon dioxide gas) inside creates pressure - that's similar to vapor pressure! When the vapor pressure equals the pressure pushing down on the liquid, we call this equilibrium vapor pressure.

How Vapor Pressure Works

Evaporation and condensation process diagram
Diagram of evaporation and condensation creating vapor pressure

Vapor pressure develops through two important processes happening at the same time:

1

Evaporation

Molecules escape from the liquid surface into the air

2

Condensation

Gas molecules return to the liquid state

3

Equilibrium

When evaporation and condensation balance each other

4

Pressure Builds

Gas molecules create pressure on container walls

The saturation vapor pressure is the maximum pressure the vapor can reach at a given temperature. When this equals the surrounding pressure, the liquid boils! This explains why water boils at lower temperatures on mountaintops (where air pressure is lower).

Factors Affecting Vapor Pressure

Factors affecting vapor pressure comparison
Illustration comparing different vapor pressures under various conditions

Several important factors determine how much vapor pressure a liquid will have:

Temperature

Higher temperature means more molecules have energy to escape, increasing vapor pressure

Intermolecular Forces

Stronger forces between molecules make it harder for them to escape, lowering vapor pressure

Nature of Liquid

Volatile liquids (like alcohol) evaporate easily and have higher vapor pressure

Raoult's Law explains how vapor pressure changes when liquids mix. The total vapor pressure depends on the mole fraction of each component. This is why adding salt to water lowers its vapor pressure - the salt molecules "get in the way" of water molecules trying to escape!

Vapor Pressure Quiz

Test your understanding with these questions about vapor pressure:

1. What creates vapor pressure in a closed container?
2. What happens to vapor pressure when temperature increases?
3. Which liquid would have the highest vapor pressure at room temperature?
4. What is equilibrium vapor pressure?
5. Why does water boil at a lower temperature on a mountain?

Frequently Asked Questions

Common questions students have about vapor pressure:

Vapor Pressure Science Facts

Discover some fascinating facts about vapor pressure:

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